Dinuclear Palladium Complex with a Bridging Dialkylsilylene Ligand
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چکیده
منابع مشابه
A Dinuclear Palladium(II) Complex of the "4266308 N(SPPh2)2"5267309 - Ligand -- Synthesis and Structure
The coordination chemistry of the anionic ligand {N(SPPh2)2} and its chalcogenide congeners {N(EPPh2)2} (E = O, Se, Te) has attracted much attention during the last two decades. In this context numerous compounds of the main group elements as well as of the transition metals and f elements were reported [1 – 6]. Due to the sulfur donor set of {N(SPPh2)2}, this ligand is considered to be a soft ...
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Hydride-abstraction reactions of hydrido(dihydrogermyl) complexes [MH(GeH2Trip)(dcpe)] [M = Pt, Pd, Trip = 9-triptycyl, dcpe = 1,2-bis(dicyclohexylphosphino)ethane] with B(C6F5)3 led to the unexpected formation of new cationic (μ-germyl)(μ-hydrido) dinuclear platinum and palladium complexes, [{M(dcpe)}2(μ-GeHTrip)(μ-H)](+).
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New dinuclear palladium(III) compounds of general formula Pd2[(C6H4)PPh2]2[N-S]2Cl2, N-S being 2-mercaptopyridinate, 3a; 2-mercapto-6-methylpyridinate, 3b; 2-quinolinethiolate, 3c; 2-mercaptopyrimidinate, 3d; 1-methyl-1H-imidazole-2-thiolate, 3e; 1-methyl-1H-benzimidazole-2-thiolate, 3f; 2-mercaptobenzothiazolate, 3g and 5-mercapto-1-methyltetrazolate, 3h have been obtained by oxidation with Ph...
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 2007
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.2007.284